REFRACTORY PROPERTIES AND CORROSION RESISTANCE OF FORSTERITE-SPINEL CERAMICS WITH UTILIZATION OF FLY ASH
DOI:
https://doi.org/10.51704/cjce.2021.vol7.iss01.pp35-43Keywords:
Forsterite, spinel, fly ash, refractoriness, corrosion resistanceAbstract
This article examines the process for the synthesis of forsterite–spinel refractory ceramics with utilization of fly ash and reactive alumina as sources of aluminium oxide. Raw materials were milled, mixed in different ratios and sintered at 1500 °C for 2 h. Sintered samples were characterized by XRD and SEM. Porosity, water absorption, bulk density, refractoriness, refractoriness under load, thermal shock resistance and corrosion resistance to the effects of molten iron were also investigated. The resulting properties were then compared depending on the source of aluminium oxide. Presence of spinel in fired samples led to improved microstructural and mechanical properties, thermal shock resistance and corrosion resistance. In particular, mixtures with 10–20 % of spinel had the most promising results.
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BUDNIKOV, P. P. a kolektiv. Technologie keramiky a žárovzdorného zboží. Praha: Státní nakladatelství technické literatury, 1960, ISBN 9780262523776.
KINGERY, W. Introduction to ceramics. New York: Wiley, 1960, xvi, 781 s. ISBN 04-714-7883-0.
ZHAO, Fei, Lixin ZHANG, Zhen REN, Jinxing GAO, Xiaoyu CHEN, Xinhong LIU a Tiezhu GE. A novel and green preparation of porous forsterite ceramics with excellent thermal isolation properties, Ceramics International, 2019, 45(3), pp. 2953-2961, ISSN 02728842, https://doi.org/10.1016/j.ceramint.2018.09.296
BOUHIFD, M. A., D. ANDRAULT, G. FIQUET a P. RICHET. Thermal expansion of forsterite up to the melting point, Geophysical research letters, 1996, 23(10), pp. 1143-1146.
HEILMANN, F.; Rixecker, G.; Börner, F.D.; Lippmann, W.; Hurtado, A. Fe2O3-doped forsterite ceramics as a joining partner for ZrO2 in a laser brazing process. Journal of European Ceramics Society, 2009, 29, pp. 2783–2789, https://doi.org/10.1016/j.jeurceramsoc.2009.03.028
MUSTAFA, E.; Khalil, N.; Gamal, A. Sintering and microstructure of spinel–forsterite bodies. Ceramics International 2002, 28, pp. 663–667, https://doi.org/10.1016/S0272-8842(02)00025-1
EWAIS, E.M.M.; El-Amir, A.A.M.; Besisa, D.H.A.; Esmat, M.; El-Anadouli, B.E.H. Synthesis of nanocrystalline MgO/MgAl2O4 spinel powders from industrial wastes. Journal of Alloys and Compounds. 2017, 691, pp. 822–833, https://doi.org/10.1016/j.jallcom.2016.08.279
KUMAR, M.S.; Vanmathi, M.; Senguttuvan, G.; Mangalaraja, R.V.; Sakthivel, G. Fly Ash Constituent-Silica and Alumina Role in the Synthesis and Characterization of Cordierite Based Ceramics. Silicon 2018, 11, pp. 2599–2611 , https://doi.org/10.1007/s12633-018-0049-0
REN, Q.; Ren, Y.; Wu, X.; Bai, W.; Zheng, J.; Hai, O. Effect mechanism of spinel (MgAl2O4) reinforced corundum ceramics on microstructure and properties. J. All. Com. 2019, 793, pp. 146–154, https://doi.org/10.1016/j.jallcom.2019.04.151
TAVANGARIAN, F.; Emadi, R. Synthesis of pure nanocrystalline magnesium silicate powder. Ceram. Silikat. 2010, 54, pp. 122–127, ISSN 1804-5847.
NGUYEN, M.; Sokolář, R. Formation and Influence of Magnesium-Alumina Spinel on Properties of Refractory Forsterite-Spinel Ceramics. Materiali in Tehnologije, 2020, 54, pp. 135–141, https://doi.org/10.17222/mit.2019.198
NGUYEN, Martin a Radomír SOKOLÁŘ. Impact of Fly Ash as a Raw Material on the Properties of Refractory Forsterite–Spinel Ceramics. Minerals. 2020, 10(9). ISSN 2075-163X. https://doi.org/10.3390/min10090835
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